Models for Bonding in Chemistry

Even though modern molecular quantum mechanics offers the natural basis for very elaborate numerical calculations, models of bonding that avoid the more mathematical aspects of the subject, in the spirit of Coulson’s Valence, are still of interest for stating elementary concepts of valence for atoms, molecules and their interactions.

Distinctive features of this book include:

• Models of bonding in molecules that mostly require the solution of quadratic equations with real roots.

• An introductory model of bonding in solids.

• A model of long-range Van der Waals interactions that avoid use of perturbation theory.

• A simple pictorial model of the electrostatic interactions that determine the shape of H-bonded dimers.

• Consistent use of atomic units from the very beginning for simplifying mathematical formulae.

• A comprehensive list of references and both author and subject indices.

The book covers, in a readable manner with minimal use of mathematics, the essentials of the different bonds occurring in chemistry. Intended for undergraduate students in chemical physics, physical, theoretical and quantum chemistry, it is also relevant to masters and postgraduate students and to any scientist or student who requires a straightforward approach to bonding in molecules and solids.